Evaluation of Chemical Properties of Polymethylmethacrylate in Two Different Media by Using Ultraviolet-Visible Spectroscopy
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Keywords

Polymethylmethacrylate
Ultraviolet Visible Spectroscopy
Denture Base Resins
Chlorine

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How to Cite

1.
Mathar MI. Evaluation of Chemical Properties of Polymethylmethacrylate in Two Different Media by Using Ultraviolet-Visible Spectroscopy . Integr J Med Sci [Internet]. 2020 Aug. 24 [cited 2024 Dec. 22];7. Available from: https://mbmj.org/index.php/ijms/article/view/201

Abstract

Aim: The aim of this study was to evaluate the effect of concentration of chlorine on the polymethylmethacrylate and the influence of chemical properties of polymethylmethacrylate using ultraviolet-visible spectroscopy.
Materials and methods: A total of 30 acrylic blocks of dimensions 65X 13X 3 mm as per the specification of ASTM [American standard for testing materials] were made in heat cure denture base resin to evaluate the effect of chlorine on polymethylmethacrylate. 30 samples were divided into 3 groups of 10 samples in each. Group, I was stored in artificial saliva which acts as a control group, Group II was stored in a 3ppm concentration of chlorine, and Group III was stored in a 100ppm concentration of chlorine.
Results: Ultraviolet rays are passed into the sample, the results are obtained on a graph with a wavelength in nanometer on the X-axis and the percentage of reflectance on the Y-axis. If an organic compound absorbs ultraviolet radiation, it means that the compound contains carbonyl or conjugated double bonds3. Since polymethylmethacrylate absorbs ultraviolet rays, the existence of these bonds is confirmed in the graph.
Conclusion: Within the limitations of the study it was concluded that the effect of chlorine on polymethylmethacrylate can react over the conjugated bond or carbonyl group at higher concentrations, whereas the action of chlorine is negligible at a lower concentrations.

https://doi.org/10.15342/ijms.7.201
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References

Rizzatti-Barbosa CM, Aurélio Fraga M, de Moraes Gonçalves T. Acrylic resin water sorption under different pressure, temperature and time conditions. J Mater Res. 2001 Jan 1; 4(1). https://doi.org/10.1590/S1516-14392001000100002

Anusavice K. Philips’ Science of Dental materials 11th edition. 2003.

Chung KH, Sahrma B, Greener EH. Polymerization kinetics in dental acrylics. Dent Mater. 1986 Dec; 2(6):275-8. https://doi.org/10.1016/s0109-5641(86)80042-2

Manual on water supply and treatment. Central Public Health Environm Engineering Organization (CPHEEO). [Accessed 2021 Oct 06]. Available from: http://cpheeo.gov.in/cms/manual-on-water-supply-and-treatment.php

Prakash S. Advanced inorganic chemistry. 16th edition. 2000.

Bansal RK. Organic reaction and mechanisms 3rd edition. Eleventh reprint; 2006.

Bhal BS, Arun B. A text book of organic chemistry 13th edition. S Chand; 2005.

Kaur H. Instrumental methods of chemical analysis. 3rd edition. Pragati Prakashan; 2010.

Eliades GC, Vougiouklakis GJ, Caputo AA. Degree Of double bond conversion in light –cured composites Dent Mater. 1987 Feb; 3(1):19-25. https://doi.org/10.1016/s0109-5641(87)80055-6

Puri BR, Sharma LR, Pathania MS. Principles of physical chemistry. Vishal Publishing Company. 2008.

Pariiskii GB, Davydov EY, Zaitseva NI, Toptygin DY. The interaction of polymethyl methacrylate with chlorine atoms formed in the photo reduction of ferric chloride. Russ Chem Bull 21. 1972; 238–244. https://doi.org/10.1007/BF00857777

Stansbury JW, Dickens SH. Determination of double bond conversion in dental resins by near infrared spectroscopy. Dent Mater. 2001 Jan;17(1):71-9. https://doi.org/10.1016/s0109-5641(00)00062-2

Sankar V, Suresh Kumar T, Panduranga Rao K. Preparation, characterization and fabrication of intraocular lens from photoinitiated polymerized poly ( methyl methacrylate). Trends biomaterials and artificial organs. 2004; 17 (2): 24-30. [Accessed 2021 Oct 06]. Available from: https://go.gale.com/ps/i.do?id=GALE%7CA165431689&sid=googleScholar&v=2.1&it=r&linkaccess=abs&issn=09711198&p=HRCA&sw=w&userGroupName=anon%7E777304f8

Nimma ER, Kalyanasundaram S, Gopalan A, Saito Y, Manuel SA. Preparation and Characterization of PVC/PMMA Blend Polymer Electrolytes Complexed with LiN(C2F5SO2)2 Polimeros :Ciencia e tecnologia. 2004 ;14(1):1-7. http://dx.doi.org/10.1590/S0104-14282004000100006

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Copyright (c) 2020 Mohammed Ibrahim Mathar

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